Enthalpy
Enthalpy (IV.D465) is the τ-categorical Energy Index plus the work-conjugate term carried by the τ-pressure on the bundle's volume mode. It is the natural energy quantity on a defect bundle held at fixed pressure — equal to E + PV in the τ-internal pairing.
τ-Definition
Enthalpy (IV.D465) is the τ-categorical Energy Index plus the work-conjugate term carried by the τ-pressure on the bundle's volume mode. It is the natural energy quantity on a defect bundle held at fixed pressure — equal to E + PV in the τ-internal pairing.
Categorical invariant. Enthalpy(B) := Energy Index(B) + ⟨τ-Pressure, Volume mode⟩(B); the natural total energy under fixed-pressure τ-boundary.
Primary registry anchor:
IV.D465
τ-Derivation Chain
-
I.K0— Universe Postulate establishes τ -
IV.D11— Physical Quantity Template — dimensional invariants -
IV.D21— Energy Index -
IV.D465— Enthalpy = E + PV under fixed-pressure τ-boundary -
IV.D482— Gibbs Free Energy = H - TS extends to the entropy-pressure conjugate pair
Lean modules referenced:
TauLib.BookIV.QuantumMechanics.EnergyEntropy
SI Translation
Calibration anchor: PG-P01-neutron
Calibration chain:
- m_n (anchor)
- c² via IV.D23
- PV term via τ-pressure conjugate pairing
Manuscript reference: manuscript-sources/book-04/part04-quantum-mechanics/ch-energy-entropy.tex